D:A-friedo-oleanane triterpenes from the stem bark of Phyllobotryon spathulatum
Identifieur interne : 00D862 ( Main/Exploration ); précédent : 00D861; suivant : 00D863D:A-friedo-oleanane triterpenes from the stem bark of Phyllobotryon spathulatum
Auteurs : Simon Gibbons ; Alexander I. Gray ; David C. R. Hockless [Australie] ; Catherine Lavaud [France] ; Jean-Marc Nuzillard [France] ; Georges Massiot [France] ; Peter G. Waterman ; Allan H. White [Australie]Source :
- Phytochemistry [ 0031-9422 ] ; 1993.
English descriptors
- KwdEn :
- Teeft :
Abstract
Abstract: Three D:A friedo-oleanane triterpenes have been isolated from the bark of Phyllobotryon spathulatum. They were characterized by the use of Heteronuclear Multiple Bond Coherence NMR spectroscopy as the known compound odolactone (3-oxo-D:A-friedo-oleanan-27,15α- lactone), and two novel friedo-oleananes, 3β-hydroxy-D:A-friedo-oleanan-27,29-dioic acid (structure confirmed by X-ray analysis of the dimethyl ester) and methyl-3-oxo-19β,21β-dihydroxy-30-nor-D:A-friedo-olean-20(29)-en-27-carboxylate.
Url:
DOI: 10.1016/S0031-9422(00)90818-5
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="en">Abstract: Three D:A friedo-oleanane triterpenes have been isolated from the bark of Phyllobotryon spathulatum. They were characterized by the use of Heteronuclear Multiple Bond Coherence NMR spectroscopy as the known compound odolactone (3-oxo-D:A-friedo-oleanan-27,15α- lactone), and two novel friedo-oleananes, 3β-hydroxy-D:A-friedo-oleanan-27,29-dioic acid (structure confirmed by X-ray analysis of the dimethyl ester) and methyl-3-oxo-19β,21β-dihydroxy-30-nor-D:A-friedo-olean-20(29)-en-27-carboxylate.</div>
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